chemistry 100
topic of the day 11-9-01
Photocopiers and Laser Printers
An application of semiconductors and photoconductivity
Background
- Materials like Silicon are normally insulators
- 4 valence electrons, 4 bonds
- Materials Changes if it absorbs light
- light frees an electron
- electron makes that region conductive
- The original Xerographic Copier
- used thin layer of Selenium
- coated on surface of a metal drum
- Modern devices use a plastic belt
- the surface is a photoconducting polymer
- the underside of the belt is metallized
- (we will talk about using a modern belt)
- Step 1-- electrically charge the surface of the belt
- (rub with cat fur? pass by high voltage electrodes?)
- Step 2-- Expose the charged surface to light
- In laser printer, small laser
- deflected by mirrors to where we want image
- In photocopier, lamp and lens
- no light around dark text
- good light near white regions of page
- Step 2 consequences
- Where illuminated,
- the plastic conducts electricity
- Where conductive,
- charge leaks though the belt
- You end up with the image as an electrical charge pattern on the belt
- Step 3-- The toner
- A fine black Powder
- Electrically charge it (other sign)
- Dust it onto the belt (or drum)
- attracted to charged areas of the image
- collect there, not on rest of the belt
- Now we have a black dust image
- looks like the original B&W image
- but it's just dust on the belt
- Step 4-- Transfer the charge to paper
- Paper is not electrically conductive
- Give paper a surface charge (opposite sign)
- Roll paper across the surface of the belt
- Paper attracts and picks up the toner
- Now, we have toner on the paper
- toner wherever the image was black
- Step 5 -- Sealing the image
- (artists in charcoal would spray a sealer to preserve the image)
- The toner is actually a polymer
- Get it hot and it softens or melts
- It sticks to the paper, permanently
- that's why fresh photocopies come out warm
- you can see that image is raised, sealed to top of paper
- can scrape off with a razor blade w/o changing paper
- (inks soak into the paper)
- (erasing involves some paper removal)
Technique developed by Carlson around 1940's
- patented-- named it xerography (dry writing)
- found no interested companies
- copies made by photography-- good enough
- Xerox machine too complex to develop ?
- one small company : Haloid
- (name from Halogen, Made Silver Halide photographic paper)
- worked with Battelle Institute, Columbus OH
- put into production, 1959 was first model
- in early 1970's production was limited
- by rabbit colonies in So. France
- Se drums scratched easily, needed cleaning
- rabbit fur was only working material
-
- Modern machines (laser printers, photocopier)
- treat drum and electrodes are disposable
- (laser printers-- fixed toner supply)
historical notes
nice step by step description with pictures
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