chemistry 100
"What Should You Know?"
Part I (9/16/01)
Background material
I'm assuming you've seen most of this, in one form or another, in a General Science, Bioogy or Chemistry Course taken before you arrived at College. Much of this is covered or used during the first two weeks of our course, although we haven't called it review.
If you have not taken any chemistry courses previously, you will need to spend some additional time on these lists in addition to what's in the textbook. If much time has elapsed since your previous course, you should also focus harder on this material. I'm not suggesting this list is simple, obvious. easily remembered or easy. It is the background you'll need to know before you approach the first exam in Chem 100.
Elements and Symbols
We will use about 25 elements and their symbols so often that you really need to know them on sight. You should recognize the
name (be able to
spell it) and know the
symbol. You should also be able to come up with the same if the symbol is given. You should also know a few
key facts about each of these.
Metals:
(being a metal is perhaps the most important fact about these elements)
- Aluminum, Al
- Copper, Cu
- reddish color
- used in bronze and brass (alloys)
- Iron, Fe
- Mercury, Hg
- a liquid at room temperature
- Lead, Pb
- Tin, Sn
- soft, melts at a low temperature, used in bronze
- Zinc, Zn
- Gold, Au
- yellow metal
- very inert (won't react)
- Silver, Ag
- Magnesium, Mg
-
Very reactive metals, gnerally found only as salts (compounds)
- Sodium, Na
- Potassium, K
- Calcium, Ca
Gases
- Hydrogen
- element occurs as H2
- burns to form water, H2O
- Oxygen, O
- about 20% of air
- present as O2
- needed for life, fire
- Nitrogen, N
- present as N2
- about 80% of air
- Helium, He
- lighter than air; balloons and blimps (really, lower density than air)
- chemically inert
Other Elements
- Chlorine, Cl
- as a gas it is Cl2
- mostly found in compounds-- like salt, NaCl
- Carbon, C
- element comes in several forms (graphite and diamond)
- found in many compounds
- Phosphorous, P
- Sulfur, S
- Silicon, Si
Try Quiz #1 -- symbols for the elements
Try Quiz #2 -- names, given the symbols
Try Quiz #3 -- properties of some elements
Naming Simple Compounds
Historical Names that don't follow any special rules
Some species, like water, have names that are almost universally used. Chemists generally don't try to name these species by chemical rules-- we just accept the common names. You need to know these names, their chemical formulas, and a few key facts about each.
-
water, H2O
- hydrogen oxide to purists
- water is the basis for the
Celsius (Centigrade) thermometer scale
- water freezes at 0 oC (32o F)
- the solid is called ice
- water boils at 100oC (212oF) under normal conditions
- the gas is called steam or water vapor
- water also was the basis of the
metric units for mass
- one
liter of water weighs 1
kg.
-
(In our archaic English system a pint of water weighs a pound, nearly)
- the
density of water is 1.0 g/ml (grams per milliliter)
-
ammonia, NH3
a gas at room temperature
- dissolves in water
- major agricultural uses (plants use as their N-source)
methane, CH4
- natural gas, swamp gas
- the simplest hydrocarbon
- burns; used as a fuel
names for carbon elemental forms
diamond, graphite, and Buckminsterfullerene (C60)
Ozone, O3
- the other form of pure oxygen
rust
rust is a major economic force
Limestone
(the mineral limestone is mainly CaCO3 )
Marble is another form of CaCO3
Try this-- Quiz on names of these species
The Chemist's Way of Naming Simple Compounds
There are, of course, a large number of compounds and the names can become very complex. Fortulately, a large number of simple compounds have smple names.
Binary Compounds -- formed from two elements
The name takes the form
[element #1] +
[root of element #2] +
ide
- examples:
- Copper Sulfide (Copper and Sulfur)
- Hydrogen Oxide (Hydrogen and Oxygen)
- Sodium Chloride (Sodium and Chlorine)
- sometimes we need some numbers, especially if the two eleents form several compounds
- carbon dioxide (di=2), CO2
- carbon monoxide (mono=1) CO
- and we avoid tongue twisters like double o's so it's
not mon
ooxide,
- phosphorous pentachloride, PCl5
- dinitrogen oxide, N2O
How do you know which element gets named first?
(There is a formal rule but some simplfied rules work well enough for our purposes.)
- metals get named as the first element
- since it's rare for two metals to form simple compounds we don't have to worry about that as a complication.
- for two elements on the same row of the periodic table, the element on the right gets named first
- The first row has B ,C , N , O , F so we'd have
- boron nitride
- carbon dioxide (not oxugen carbide)
- nitrogen oxides
- carbon tetrafluoride, CCl4
- the second row has Al , Si , P , S , Cl
- Aluminum Sufide, Al2S3
- Phosphorous pentachloride, PCl5
- Silicon tetrachloride, SiCl4
- the simple rule doesn't tell us the right order for
- Silicon dioxideSiO2
- Sulfur dioxide SO2
- the rule also doesn't tell us how to predict the numerical prefixes or chemical formulas
Common Ions with Two Elements
A very common occurance is for two elements to combine to forms a stable ion. We then find chemical compounds from such an ion and the ion of a simple element.
Let's list seven important ions
Notice the elements, the number of atoms of each and the overall charge of the ion.
You will need to know these 7 ions by name and formula
- Ammonia, NH4+ (the inly + ion in our list)
- Hydroxide, OH-
- Nitrate, NO3-
- Carbonate, CO32-
- Bicarbonate, HCO3-1 (here bi- doesn't really mean 2)
- Sulfate, SO42-
- Phosphate, PO43-
Now, let's name some of these compounds
- They are all salts or ionic compounds
- (For now, ignore the numbers)
- (note that we use parenthses for more than one)
- Sodium Hydroxide, NaOH
- Calcium Hydroxide, Ca(OH)2
- Aluminum Sulfate Al2(SO4)3
- Magnesium Carbonate MgCO3
- Ammoium Chloride, NH4 Cl
- Ammonium Nitrate NH4 NO3
- Ammonium Sulfate (NH4 )2 SO4
- Sodium Bicarbonate NaHCO3
- Potassium Carbonate K2CO3
The Metric System of Measurements
The entire world, exept for the US, uses the metric system of measurement. The scientific community in the US also uses the Metric System exclusively. Yoiu will need to knw the basics of the metric system.
We can, of course, convert measuremetns form one system to another. In this course we will seldom do such conversions. Instead, we will try to think in the metric system and provide approximate English units where that helds you get a better feel for amounts.
The beauty of the Metric System is that it is based on multiples of 10.
- kilo=1000 a kilogram contains 1000 grams
- milli = 1/1000 a millimeter is 1/1000 meter
- deciiliter = 0.1 liter
- The English system we use is based on multiples of ...
- sometimes 12 (inches/foot)
- sometimes three (feet per year)
- sometimes 16 (oz per pound, except for precisous metals where there are 12 oz/pound)
- sometimes 2000 (pounds per ton), 5280 (feet per mile), 4 (quarts per gallon)
-
The basic metric units are
-
volume: the liter
- a liter is approximatly equal to a US quart or two pints
- you can hold a container in your hands, but it's a hanful
-
mass: the kilogram or the gram
- a liter of water has a mass of about a kilogram
- you can lift and hold several kilograms with comfort
- a kilogram is 2.2 pounnds for comparison
- a gram is obviously 1/1000 or a kilogram
- a gram is a small but still perceptable mass
- a nickel weighs quate close to 5 grams
- a few pastage stamps might wiegh an ounce
- a milliliter of water has a mass of 1 gram
-
length: the meter
- a meter is a litle larger than a US yard (about 39 inches)
- your little finger is about 1 cm (1/100 meter) in width
- a flea is about 1 mm in size (1/1000 meter)
-
volume: the direct measurement of volume would be cubic meters
- a cubic meter is fairly large-- the corner stone of a building (1 meter on a side)
- we are more likely to think in cc or cubic centimeters
- this might be the volume of the part of your little finger below the nail
- 5 aspirin tables might have a volume of about 1 cc
- 1 cc is about 20 drops of liquid
- 1 cc is almopst exatly 1 milliliter
- a pop bottle might contain 350 ml
- 1 liter is 1000 ml
-
time: the unit is the second (same as what we are used to)
- metric system does recognize minutes, hours and days
-
-
-
Density (Mass/Volume)
-
Not formally part of the metric system
In the metric system, water has a density of 1.0 g / ml. A convensient number)
- A few other representative densities
- gasoline about 0.7 g/ml (will float on water)
- wood (oak) about 0.9 g/ml (also floats)
- copper metal
- Titanium Metal (often chosen because of its low density)
- mercury 13.6 g/ml.
- limestone about 2.2-2.5 g/ml
- concrete about 2.4 g / ml or 2400 kg/m3
- air -- about 1 gram / liter (about 1/1000 the densitry of water)
- try an estimate-- how much would a sidewalk slab weigh?
- consider a piece 1 meter by 1 meter (a small sidewalk piece)
- it's usually made about 4 " thck (2.54 cm per inch so it's about 10 cm thick)
- 10 cm = 0.10 meters
- volume is 1.0 meter x 1.10 meter x 0.1 meter = 0.1 meter3
- with a density of 2400 kg/m3 that's 240 kg
- at 2.2 lbs/kg that's about 520 lbs (about six 80 pound bags of concrete)
-
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